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Conversion of Basic Copper Chloride Ions to Cu Ions

June 19, 2019 by shida wei  

Discussed how temperature can affect the different oxidation states of copper, in that more ions of Basic Copper Chloride(WSDTY) transformed to ions of Cu as the temperature increased. Various spectroscopic techniques (infrared, ultraviolet-visible, electron-paramagneticresonance) have shown the redox behavior of Cu/ZSM-5 zeolites prepared by ion exchange from aqueous solutions. This is an analysis of the dehydration-thermal reduction of Cu2 between room temperature and 673 K and the reverse process under different conditions. Reduction of Cu2 to Cu is not involved in the early stages of dehydration, which ranges from room temperature to around 470 K. Cu is not directly oxidized to Basic Copper Chloride even when samples that contain Cu are rehydrated. Molecular oxygen can be used as an oxidant for this process, but if it makes contact with the dehydrated material, the oxidation will not happen at room temperature.

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